On the mechanism of oxidation of decahydronaphthalene at 100oC

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Decalin (decahydronaphthalene, also known as bicyclo[]decane and sometimes decaline), a bicyclic organic compound, is an industrial solvent.A colorless liquid with an aromatic odor, it is used as a solvent for many resins or fuel additives.

Details On the mechanism of oxidation of decahydronaphthalene at 100oC EPUB

It is the saturated analog of naphthalene and can be prepared from it by hydrogenation in the presence of a ein Reference: 1. Can J Res.

Feb;27(2) On the mechanism of oxidation of trans-decahydronaphthalene at degrees C. McARTHUR DS, SMITH EA. PMID:Cited by: 1. Predicted data is generated using the US Environmental Protection Agency’s EPISuite™. Log Octanol-Water Partition Coef (SRC): Log Kow (KOWWIN v estimate) = Boiling Pt, Melting Pt, Vapor Pressure Estimations (MPBPWIN v): Boiling Pt (deg C): (Adapted Stein & Brown method) Melting Pt (deg C): (Mean or Weighted MP) VP(mm Hg,25 deg.

Decahydronaphthalene definition is - a colorless liquid hydrocarbon C10H18 obtained by hydrogenation of naphthalene and used as a solvent (as for paints, lacquers, and silicones). Decahydronaphthalene definition, a colorless, aromatic liquid, C10H18, insoluble in water and soluble in alcohol and ether: used as a solvent for oils, fats, etc., in.

Various zeolite-alumina composites supported NiMo catalysts were prepared and their properties for hydrocracking of a decahydronaphthalene (decalin) solution containing 10 wt.% of 1-methylnaphthalene (1-MN) and wt.% of dibenzothiophene were investigated in order to estimate not only hydrocracking of hydrocarbons but also isomerization and hydrogenation of Cited by:   It is shown that the electrochemical oxidation of esters of 2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylic acids in anhydrous acetonitrile takes place as a one-electron process, while the final products of the transformations (pyridines or pyridinium salts) are formed as a result of disproportionation of the intermediate radicals.

When 1–2% (by volume) water is Author: Ya. Ogle, Ya. Stradyn, G. Dubur, V. Lusis, V. Kadysh. The electrocatalytic oxidation of NADH by ferrocene derivatives and the influence of the complexation reaction of β-cyclodextrin (β-CD) were investigated in a buffered solution (pH ).

From the cyclic voltammetric behaviour, the electron-transfer rate constants from NADH to the ferricinium species were by: Saturated aliphatic hydrocarbons, such as DECAHYDRONAPHTHALENE, may be incompatible with strong oxidizing agents like nitric acid.

Charring of the hydrocarbon may occur followed by ignition of unreacted hydrocarbon and other nearby combustibles. In other settings, aliphatic saturated hydrocarbons are mostly unreactive. Recently, we disclosed a method for the direct coupling of acyclic dienes to carbonyl partners from the alcohol or aldehyde oxidation level to furnish branched products of carbonyl addition with complete levels of regiocontrol.

4a Thus, 1,3-butadiene, isoprene and 2,3-dimethylbutadiene were found to deliver products of carbonyl crotylation Cited by: give low enantioselectivities in bifunctional organocatalyzed nitro-Mannich reactions,4a making it unsuitable for this study.

In addition, N-Boc- and N-phosphinoyl-protected substrates. Decahydronaphthalene Information about Decahydronaphthalene is for educational purposes only. ALS Environmental provides no warranty, expressed or implied, as to the accuracy, reliability or completeness of furnished data.

ALS Environmental is a laboratory testing network and is not affiliated with the U.S. Department of Transportation, the. (organic chemistry) A bicyclic cycloalkane consisting of two fused cyclohexane rings; it is used as an industrial solvent.

Decahydronaphthalene, also known as decalin, is a bicyclic organic compound that is a colorless liquid with an aromatic odor and used as an industrial solvent.

Description On the mechanism of oxidation of decahydronaphthalene at 100oC FB2

Ungraded products supplied by Spectrum are indicative of a grade suitable for. Anodic Oxidation of COads Derived from Methanol on Pt Electrocatalysts Linked to the Bonding Type and Adsorption Site Article in Electrochimica Acta – July with 49 Reads.

This page contains information on the chemical Decahydronaphthalene including: 1 synonyms/identifiers; U.S. Code of Federal Regulations Title 49 Section shipping regulations and proper shipping name; USDOT Emergency Response Guidebook initial.

Decahydronaphthalene. decahydronaphthalene, bicyclo[]decane, Dec, decalin, dekalin, naphthan, perhydronaphthalene, dekalina, naphthalane, naphthane, decaline.

The LD50 value (oral) of decahydronaphthalene in male rats was estimated to be mg/kg bw based on a 14 day observation period. Thus the test substance showed a. The mechanism of electrochemical oxidation of catechol (1a), 3-methylcatechol (1b) and 3-methoxycatechol (1c) in the presence of benzenesulfinic acid (3).

Mixed bacterial cultures aerobically transformed decalin (decahydronaphthalene) dissolved in an immiscible carrier phase (heptamethylnonane; HMN) in liquid medium. Conversion was enhanced in the presence of decane, a readily degraded n-alkane, and/or HMN.

Four Rhodococcus spp. isolates purified from one of the mixed cultures were active against decalin Cited by: 6. Oxidation reduction potential in mV at 20°C provides substance information on the substance’s oxidation reduction measured in millivolts at a temperature of 20°C.

Type of study provided This section provides an overview of the type of study records behind the presented results and – if applicable - data waving justifications.

Friedel−Crafts alkylation reactions of biphenyl with (dichloroalkyl)chlorosilanes [Cl3-mMemSi(CnH2n-1Cl2), m = 0−2, n = 1−3] at temperatures ranging from to °C in the presence of a Lewis acid catalyst gave cyclized products, fluorenyl-substituted chlorosilanes, in 47−94% yields.

In these reactions, the reactivities of (dichloroalkyl)silanes generally increase Cited by: 4. (m3/ug)): Mackay model: E Octanol/air (Koa) model: E Fraction sorbed to airborne particulates (phi): Junge-Pankow model: E Mackay model: E Octanol/air (Koa) model: E Atmospheric Oxidation (25 deg C) [AopWin v]: Hydroxyl Radicals Reaction: OVERALL OH Rate Constant = E cm3/molecule-sec.

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Chemistry Stack Exchange is a question and answer site for scientists, academics, teachers, and students in the field of chemistry. Allylic Radicals Bromination Mechanism. Ask Question Asked 5 years, 7 months ago. Browse other questions tagged organic-chemistry reaction-mechanism or ask your own question.

Dissolution process of polystyrene in decahydronaphthalene solution was conducted and compared under different conditions. The effects of dissolution time and temperature on the dissolution ratio of polystyrene were performed with the assistance of ultrasonic and mechanical agitation, respectively.

The dissolution ratio of polystyrene increased with the increment of Author: Jia Jia Wang, Hui Huang, Ting Li, Shi Ying Tao. Model tetraenal 9b underwent intramolecular Diels–Alder cycloaddition in CH 2 Cl 2 at −10 °C under catalysis by the bulky Lewis acid B(C 6 F 5) 3 to deliver as major components the cis-fused angularly-methylated octahydronaphthalene products, which are formed through the alternative exo orientations of the reacting moieties.

One of these diastereomers features the relative and Cited by: 1. Definition of decahydronaphthalene in the dictionary. Meaning of decahydronaphthalene. What does decahydronaphthalene mean. Information and translations of decahydronaphthalene in the most comprehensive dictionary definitions resource on the web.

Triethylamine and TBD supported on silica: useful heterogeneous catalysts for the reaction of β-dicarbonyl derivatives with α,β-unsaturated compounds under batch and continuous flow conditions Raimondo Maggi,* Calogero G.

Piscopo, and Giovanni Maestri “Clean Synthetic Methodology Group”, Dipartimento d i Chimica dell’Università. SAFETY DATA SHEET Revision Date Jan Revision Number 3 1.

Identification Product Name Decahydronaphthalene-d18, packaged in ampules Cat No.: AC CAS-No Synonyms No information available Recommended Use Laboratory chemicals. Uses advised against Food, drug, pesticide or biocidal product use. Details of the supplier of the.

Draw the major product formed when the structure shown below undergoes free-radical bromination. Remember that bromination is highly selective. MSDS Name: Decahydronaphthalene Catalog Numbers: D, D, O NTP found clear evidence of carcinogenicity in male rats. However, the mechanism is not relevant to humans.

NTP found no evidence of carcinogenicity in female rats, no evidence in male mice, and equivocal evidence in female mice. Section 4 - First Aid Measures.Decahydronaphthalene is observed at m-' and for cis Decahydmnapthalene at cm-'. The observed frequencies for C-H sbetching at,and cm-' are the same for these two compounds.

A close look at the observed frequencies of .A sulfur-containing auxiliary enabled palladium-catalyzed C(carbonyl)–C bond activation of amides was reported to form phenylcarbamate derivatives with alcohols.

Both alkyl and benzyl alcohols could be employed well with yields up to 85%. Derivations from phenylcarbamates to ureas and thiocarbamates illustraCited by: 1.